Issue 3, 2015
From the journal:

Chemical Communications

Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis†

Grant A. Edwards,a   Phillip A. Culpa  and  Justin M. Chalker*a  

* Corresponding authors

a The University of Tulsa, Department of Chemistry and Biochemistry, 800 South Tucker Drive, Tulsa, Oklahoma 74104, USA
E-mail: justin-chalker@utulsa.edu

Abstract

Allyl sulphides are reactive substrates in ruthenium-catalysed olefin metathesis reactions, provided each substrate is matched with a suitable catalyst. A profile of catalyst activity is described, along with the first demonstration of allyl sulphides as traceless promoters in relayed ring-closing metathesis reactions.

Graphical abstract: Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

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Article information

DOI
https://doi.org/10.1039/C4CC07932A
Article type
Communication
Submitted
08 Oct 2014
Accepted
12 Nov 2014
First published
20 Nov 2014

Chem. Commun., 2015,51, 515-518

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Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

G. A. Edwards, P. A. Culp and J. M. Chalker, Chem. Commun., 2015, 51, 515 DOI: 10.1039/C4CC07932A

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