Issue 2, 2019
From the journal:

Green Chemistry

A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL†

Hamed Mahmoudi,‡ab   Federica Valentini,‡a   Francesco Ferlin,a   Lucia Anna Bivona,c   Ioannis Anastasiou,a   Luca Fusaro,c   Carmela Aprile,c   Assunta Marrocchia  and  Luigi Vaccaro ORCID logo *a  

* Corresponding authors

a Laboratory of Green S.O.C. – Dipartimento di Chimica, biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto 8, 06123 – Perugia, Italy
E-mail: luigi.vaccaro@unipg.it
Web: http://www.dcbb.unipg.it/greensoc

b Chemistry Department, Sharif University of Technology, Tehran, P.O. Box 11155-3615, Iran

c Laboratory of Applied Material Chemistry (CMA), University of Namur, 61 rue de Bruxelles, 5000 Namur, Belgium

Abstract

The [PdCl4]2− palladium complex has been immobilized on a polystyrene-type resin loaded with pincer-type imidazolium ionic tag binding sites. The catalytic system (Pd(II)-POLI-TAG) has proved to be highly active in the definition of an efficient protocol for the Heck–Mizoroki coupling reaction under batch and flow conditions. Importantly, it is shown to be highly robust in combination with a safe non-toxic reaction medium, i.e. biomass-derived GVL, since it could be reused for multiple runs without significantly losing its activity.

Graphical abstract: A tailored polymeric cationic tag–anionic Pd(ii) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8GC03228A
Article type
Paper
Submitted
14 Oct 2018
Accepted
13 Dec 2018
First published
21 Dec 2018

Green Chem., 2019,21, 355-360

Permissions

Request permissions

A tailored polymeric cationic tag–anionic Pd(II) complex as a catalyst for the low-leaching Heck–Mizoroki coupling in flow and in biomass-derived GVL

H. Mahmoudi, F. Valentini, F. Ferlin, L. A. Bivona, I. Anastasiou, L. Fusaro, C. Aprile, A. Marrocchi and L. Vaccaro, Green Chem., 2019, 21, 355 DOI: 10.1039/C8GC03228A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements